Invited talk
Radicalism and π-magnetism in carbon-based nanostructures
David Écija
IMDEA Nanociencia, 28049, Madrid, Spain
The synthesis of π-conjugated nanostructures on surfaces and the emergence of π-radicals is a thrilling topic of research, provided the potential exchange magnetic coupling to be established between the radicals [1,2]. I will present our recent findings [3-6] regarding the expression, measurement and maximization of the magnetic exchange coupling between unpaired spins of carbon atoms, which is a key magnitude for potential future application in nanomagnetism of such on-surface synthesized compounds.
[1] J, Li et al., Nat. Commun. 10, 200 (2019).
[2] D.G. de Oteyza et al., J. Phys. Cond. Matter, 34 443001 (2022).
[3] K. Biswas et al., J. Am. Chem. Soc. 145, 2968 (2023).
[4] K. Biswas et al., J. Am. Chem. Soc. 144, 12725 (2022).
[5] K. Biswas et al., Angew. Chem. Int. Ed. 61, e202114983 (2022).
[6] A. Sánchez-Grande et al., J. Phys. Chem. Lett. 12, 330-336 (2021).